Oxidative Liquid-Phase Detoxification of Organochlorous Components of Wastewater
https://doi.org/10.18412/1816-0395-2026-8-
Abstract
The possibilities of creating high-activity low-percentage ruthenium catalysts based on the (Ru+CeO2 +ZrO2)/C system for the neutralization of highly toxic organochlorine components of wastewater by the method of liquid-phase oxidation with atmospheric oxygen are considered. Shown that the use of Ru-CeO2-ZrO2 – carbon catalysts with a low content of Ru (up to 0.6 % wt.) and with a high dispersion of particles of both the active component and the promoter, makes it possible to achieve high degrees (up to 95 %) of water purification from dissolved organochlorine substances at relatively low temperatures (160–180 °C). The ability of catalysts to synthesize the active component in the studied reaction mixtures during testing.
Keywords
About the Authors
N. M. DobrynkinRussian Federation
Cand. Sci. (Chem.)
M. V. Batygina
Russian Federation
1st Category Engineer
References
1. Джирард Д.Е. Основы химии окружающей среды. Пер. с англ. В.И. Горшкова; под ред. В.А. Иванова. М., Физматлит, 2008. 640 с.
2. Bhargava S.K., Tardio J., Prasad J. et al. Wet oxidation and catalytic wet oxidation. Industrial & engineering chemistry research. 2006. Т. 45. №. 4. Р. 1221—1258.
3. Пармон В.Н., Симонов А.Д., Садыков В.А., Тихов С.Ф. Каталитическое сжигание: достижения и проблемы. Физика горения и взрыва. 2015. Т. 51. №. 2. С. 5—13.
4. Levec J., Pintar A. Catalytic wet-air oxidation processes: A review. Catalysis Today. 2007. Т. 124. №. 3—4. Р. 172—184.
5. Bethi B., Sonawane S. H., Bhanvase B. A. et al. Nanomaterials- based advanced oxidation processes for wastewater treatment: A review. Chemical Engineering and Processing- Process Intensification. 2016. Т. 109. Р. 178—189.
6. Kim K.H., Ihm S.K. Heterogeneous catalytic wet air oxidation of refractory organic pollutants in industrial wastewaters. А review. Journal of Hazardous Materials. 2011. Т. 186. №. 1. Р. 16—34.
7. Jing G., Luan M., Chen T. Progress of catalytic wet air oxidation technology. Arabian journal of Chemistry. 2016. Т. 9. Р. S1208—S1213.
8. Kumari M., Saroha A.K. Performance of various catalysts on treatment of refractory pollutants in industrial wastewater by catalytic wet air oxidation. A review. Journal of environmental management. 2018. Т. 228. Р. 169—188.
9. Arena F., Di Chio R., Gumina B. et al. Recent advances on wet air oxidation catalysts for treatment of industrial wastewaters. Inorganica Chimica Acta. 2015. Т. 431. Р. 101—109.
10. Li D., Wang D., Jiang Z. Catalytic wet air oxidation of sewage sludge. А review. Current Organocatalysis. 2020. Т. 7. №. 3. Р. 199—211.
11. Zazou H., Oturan N., Sцnmez-Зelebi M. et al. Mineralization of chlorobenzene in aqueous medium by anodic oxidation and electro-Fenton processes using Pt or BDD anode and carbon felt cathode. Journal of Electroanalytical Chemistry. 2016. Т. 774. Р. 22—30.
12. Zazou H., Oturan N., Sцnmez-Зelebi M. et al. Cold incineration of 1, 2-dichlorobenzene in aqueous solution by electrochemical advanced oxidation using DSA/Carbon felt, Pt/Carbon felt and BDD/Carbon felt cells. Separation and Purification Technology. 2019. Т. 208. Р. 184—193.
13. Lao Y., Zhu N., Jiang X. et al. Effect of Ru on the activity of Co3O4 catalysts for chlorinated aromatics oxidation. Catalysis Science & Technology. 2018. Т. 8. №. 18. Р. 4797—4811.
14. Zhang Y., Zhu M., Wei Q. et al. Removing chlorobenzene via the synergistic effects of adsorption and catalytic oxidation over activated carbon fiber loaded with transition metal oxides. Atmosphere. 2022. Т. 13. №. 12. Р. 2074.
15. Pan C., Zhang Q., Zhang W. et al. Wet scrubbing coupled with advanced oxidation process for removal of chlorobenzene: A study of performance and mechanisms. Environmental Research. 2025. Т. 268. Р. 120779.
16. Sun X., Gu X., Lyu S. The performance of chlorobenzene degradation in groundwater: comparison of hydrogen peroxide, nanoscale calcium peroxide and sodium percarbonate activated with ferrous iron. Water Science and Technology. 2021. Т. 83. №. 2. Р. 344—357.
17. Oturan M.A., Aaron J.J. Advanced oxidation processes in water/wastewater treatment: principles and applications. A review. Critical reviews in environmental science and technology. 2014. Т. 44. №. 23. Р. 2577—2641.
18. Saravanan A., Deivayanai V.C., Kumar P.S. et al. A detailed review on advanced oxidation process in treatment of wastewater: Mechanism, challenges and future outlook. Chemosphere. 2022. Т. 308. Р. 136524.
19. Yadav S., Kumar S., Haritash A.K. A comprehensive review of chlorophenols: Fate, toxicology and its treatment. Journal of environmental management. 2023. Т. 342. Р. 118254.
20. Gu Y., Cai T., Gao X. et al. Catalytic combustion of chlorinated aromatics over WOx/CeO2 catalysts at low temperature. Applied Catalysis B: Environmental. 2019. Т. 248. Р. 264—276.
21. Борисов В.А., Иост К.Н., Петрунин Д.А. и др. Влияние природы модификатора на каталитические свойства и термическую стабильность катализаторов разложения аммиака Ru—Cs (Ba)/сибунит. Кинетика и катализ. 2019. Т. 60. №. 3. С. 394—402.
22. Левинский М.И., Мазанко А.Ф., Новиков И.Н. Хлористый водород и соляная кислота. М., Химия, 1985. 160 с.
Review
For citations:
Dobrynkin N.M., Batygina M.V. Oxidative Liquid-Phase Detoxification of Organochlorous Components of Wastewater. Ecology and Industry of Russia. 2026;30(8). (In Russ.) https://doi.org/10.18412/1816-0395-2026-8-
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