Conversion of CO2 into Synthetic Motor Fuels
https://doi.org/10.18412/1816-0395-2024-11-4-9
Abstract
The process of CO2 conversion into synthetic hydrocarbons including the stages of synthesis gas production on the catalyst NIAP 06-06 and hydrocarbon synthesis by the Fischer-Tropsch method on a bifunctional zeolite-containing catalyst has been investigated. Experimental studies of the process of catalytic conversion of CO2 into synthesis gas were carried out in order to obtain gas with the ratio of H2/CO close to the required ratio for Fischer-Tropsch synthesis. The possibility of obtaining gasoline and diesel fractions of hydrocarbons with a high content of isomeric structures that increase the performance characteristics of motor fuels has been shown. The yield of hydrocarbons C5+ with 1 m3 of initial CO2 and H2 at the synthesis temperature of 220 °C is found to be 44.5 g.
About the Authors
I.N. ZubkovRussian Federation
Cand. Sci. (Eng.), Associate Professor
A.N. Saliev
Russian Federation
Cand. Sci. (Eng.), Associate Professor
M.A. Zubkova
Russian Federation
Technician of the Research Institute “Nanotechnologies and New Materials”
D.V. Telegin
Russian Federation
Technician of the Research Institute “Nanotechnologies and New Materials”
O.P. Papeta
Russian Federation
Research Engineer of the Research Institute “Nanotechnologies and New Materials”
A.V. Dulnev
Russian Federation
Cand. Sci. (Eng.), Technical Director
R.E. Yakovenko
Russian Federation
Cand. Sci. (Eng.), Director of the Research Institute “Nanotechnologies and New Materials"
References
1. Dziejarski B., Krzyżyńska R., Andersson K. Current status of carbon capture, utilization, and storage technologies in the global economy: A survey of technical assessment. Fuel. 2023. Vol. 342. Р. 127776.
2. Lange J.P. Towards circular carbo-chemicals—the metamorphosis of petrochemicals. Energy & Environmental Science. 2021. Vol. 14. № 8. Р. 4358—4376.
3. Kamkeng A.D., Wang M., Hu J., Du W., Qian F. Transformation technologies for CO2 utilisation: Current status, challenges and future prospects. Chemical Engineering Journal. 2021. Vol. 409. Р. 128138.
4. Shah M.A., Shibiru A.L., Kumar V., Srivastava V.C. Carbon dioxide conversion to value-added products and fuels: opportunities and challenges: a critical review. International Journal of Green Energy. 2023. Р. 1—20.
5. Dieterich V., Buttler A., Hanel A., Spliethoff H., Fendt S. Power- to-liquid via synthesis of methanol, DME or Fischer—Tropsch-fuels: a review. Energy & Environmental Science. 2020. Vol. 13. № 10. Р. 3207—3252.
6. Kaiser P., Unde R.B., Kern C., Jess A. Production of liquid hydrocarbons with CO2 as carbon source based on reverse water-gas shift and Fischer‐Tropsch synthesis. Chemie Ingenieur Technik. 2013. Vol. 85. № 4. Р. 489—499.
7. Visconti C.G., Martinelli M., Falbo L., Fratalocchi L., Lietti L. CO2 hydrogenation to hydrocarbons over Co and Fe-based Fischer-Tropsch catalysts. Catalysis Today. 2016. Vol. 277. Р. 161—170.
8. Xiong L., Liu S., Men Y., Li L., Niu X., Guo K., Xu J., An W., Wang J., Cong Y. Highly selective hydrogenation of CO2 to C5+ hydrocarbons over Fe catalysts copromoted by K with Pd. Journal of Environmental Chemical Engineering. 2022. Vol. 10. № 5. Р. 108407.
9. Ra E.C., Jang S., Oh D.G., Lee J.H., Kim H.E., Kim E.H., Kim K.Y., Lee M.H., Kim K.H., Kwak J.H., Lee J.S. A versatile hybrid catalyst platform of Na/ZnFe2O4 and zeolite for selective hydrocarbon production from CO2 hydrogenation. Chemical Engineering Journal. 2023. Vol. 470. Р. 144335.
10. Yakovenko R.E., Zubkov I.N., Papeta O.P., Kataria Y.V., Bakun V.G., Svetogorov R.D., Savost’yanov A.P. The influence of platinum on the catalytic properties of bifunctional cobalt catalysts for the synthesis of hydrocarbons from CO and H2. Catalysts. 2024. Vol. 14. 351.
11. Зубков И.Н., Салиев А. Н., Тимохина М.А., Лавренов С.А., Иванова Т.Г., Таранушич В.А., Яковенко Р.Е. Теоретические и экспериментальные исследования конверсии СО2 в синтез-газ. Известия высших учебных заведений. Северо-Кавказский регион. Технические науки. 2023. № 3(219). С. 59—64.
12. Pour A.N., Hosaini E., Izadyar M., Housaindokht M.R. Particle size effects in Fischer-Tropsch synthesis by Co catalyst supported on carbon nanotubes. Chinese Journal of Catalysis. 2015. Vol. 36. № 8. Р. 1372—1378.
13. Ay S., Ozdemir M., Melikoglu M. Effects of metal promotion on the performance, catalytic activity, selectivity and deactivation rates of Cu/ZnO/Al2O3 catalysts for methanol synthesis. Chemical Engineering Research and Design. 2021. Vol. 36. 175. Р. 146—160.
14. Khodakov A.Y., Chu W., Fongarland P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels. Chemical reviews. 2007. Vol. 107. № 5. Р. 1692—1744.
Review
For citations:
Zubkov I., Saliev A., Zubkova M., Telegin D., Papeta O., Dulnev A., Yakovenko R. Conversion of CO2 into Synthetic Motor Fuels. Ecology and Industry of Russia. 2024;28(11):4-9. (In Russ.) https://doi.org/10.18412/1816-0395-2024-11-4-9