

Energy Efficient Technology for Processing Fine-grained Carbonaceous Wastes into Spherical Carbon Adsorbents
https://doi.org/10.18412/1816-0395-2023-6-10-16
Abstract
The technical and technological processing features of fine-grained carbonaceous technological waste into environmentally friendly products with significant energy and resource saving were introduced. The article defines products which are the recycled highly efficient and competitive spherical activated carbons produced by high-speed pelletisation in aqueous medium with various hydrocarbon binders. The article describes the step-by-step manufacturing of spherical pellets by high-speed components mixing in aqueous medium. The main production parameters of spherical activated carbons (SAC) from the introduced raw materials, the formulation (ratio of components), the conditions for pelletisation and subsequent high-temperature carbonization and activation were identified. The parameters of the porous structure, sorption properties and technical features of the obtained materials were assessed according to the methods typical for the validation of activated carbons. It was confirmed that the characteristics of developed SAC were not inferior to industrial activated carbons in terms of porous structure and sorption properties, and significantly exceed them in terms of percentage of ash and endurance capability.
About the Authors
V.V. SamoninRussian Federation
Dr. Sci. (Eng.), Head of Department
V.N. Solovey
Russian Federation
Cand. Sci. (Eng.), Senior Lector
References
1. Соловей В.Н., Самонин В.В., Спиридонова Е.А., Хрылова Е.Д. Применение жидкостной грануляции для получения углеродных сорбентов сферической формы. Известия СПбГТИ(ТУ). 2015. № 31. С. 84—85.
2. Соловей В.Н., Спиридонова Е.А., Самонин В.В., Хрылова Е.Д., Подвязников М.Л. Получение гранулированного углеродного сорбента сферической формы. Журнал прикладной химии. 2016. Т. 89. № 7. С. 908—915.
3. Gryglewicz G., Grabas K., Lorenc-Grabowska E. Preparation and characterization of spherical activated carbons from oil agglomerated bituminous coals for removing organic impurities from water. Carbon. 2002. V. 40. Is. 13. P. 2403—2411.
4. Amorós-Pérez A., Cano-Casanova L., Ouzzine M., Rufete-Beneite M., José Romero-Anaya A, Lillo- Ródenas M.Á., Linares-Solano Á. Spherical activated carbons with high mechanical strength directly prepared from selected spherical seeds. Materials. 2018. V. 11(5). Р. 770.
5. Won-Chun O., Jong-Gyu K., Hyuk K., Ming-Liang C., Feng-Jun Z., Kan Z., Ze-Da M. Preparation of spherical activated carbon and their physicochemical properties /. Journal of the Korean Ceramic Society. 2009. V. 46. Is. 6. P. 568—573.
6. Мурко В.И., Кравченко А.Е., Бондаренко А.Н., Заостровский А.Н. Обогащение тонких угольных шламов методом масляной грануляции. Вестник Кузбасского государственного технического университета. 2020. № 4. С. 42—48.
7. Авдохин В. Обогащение углей. Том 1. Процессы и машины. М., Горная книга, 2017. 425 c.
8. Бабенко С.А., Семакина О.К., Миронов В.М., Чернов А.Е. Гранулирование дисперсных материалов в жидких средах (Элементы теории, практика, перспективы применения). Томск, Издательство Института оптики атмосферы СО РАН, 2003. 346 с.
9. Zengxue L., Jifeng Y., Mingzhen W., Meilian H., Dawai L. Coal accumulation zones and their contribution to the enrichment of multi-energy source deposits in the Ordos Basin. Energy Exploration & Exploitation Sage Publications, Ltd. 2006. V. 24. N. 3. Р. 171—179.
10. Елишевич А.Т., Папушин Ю.Л., Белецкий В.С. Обогащение угольных шламов методом масляной агломерации. Кокс и химия. 1991. № 5. С. 7—9.
11. Hapgood K.P., Litster J., Smith R. Nucleation regime map for liquid bound granules. AIChE Journal. 2003. V. 49. № 2. Р. 350—361.
12. Клейн М.С., Байченко А.А., Почевалова Е.В. Обогащение и обезвоживание тонких угольных шламов с использованием метода масляной грануляции. Горный информационно-аналитический бюллетень (научно-технический журнал). 2002. №4. С. 237—239.
13. Abberger T., Seo A., Schafer T. The effect of droplet size and powder particle size on the mechanisms of nucleation and growth in fluid bed melt agglomeration. International Journal of Pharmaceutics. 2002. V. 249. P. 185—197.
Review
For citations:
Samonin V., Solovey V. Energy Efficient Technology for Processing Fine-grained Carbonaceous Wastes into Spherical Carbon Adsorbents. Ecology and Industry of Russia. 2023;27(6):10-16. (In Russ.) https://doi.org/10.18412/1816-0395-2023-6-10-16