

Criteria for the Selection of Synthetic Polymeric Waste as a Raw Material for Producing Carbon Sorbents with Predetermined Properties
https://doi.org/10.18412/1816-0395-2020-10-13-19
Abstract
The results of studies on the thermal processing of synthetic multi-tonnage polymeric waste (polypropylene, polycarbonate, textolite, PET, organoplastics and tire rubber) with the production of carbon sorbents for technological and environmental purposes are presented. The influence of the nature of the activating agent and the conditions of the process with the production of sorbents with predetermined properties was studied. Analysis of the research results allowed us to establish that the main factors affecting the yield of carbonizate and the formation of a porous structure of carbon sorbents from synthetic polymer waste are the degree of aromaticity and the location of benzene rings in the polymer structure, the proportion of oxygen in the precursor. The criteria for selecting synthetic polymer wastes as raw materials for obtaining carbon sorbents with predetermined properties are established. The results of the research can be used in the development of technologies for obtaining carbon sorbents with predetermined properties from waste synthetic polymers and the selection of technological parameters for processes.
About the Authors
Ya.I. VaismanRussian Federation
Dr. Sci. (Med.), Research supervisor of Department of "Environmental Protection"
I.S. Glushankova
Russian Federation
Dr. Sci. (Eng.), Professor
L.V. Rudakova
Russian Federation
Dr. Sci. (Eng.), Head of Department
A.A. Surkov
Russian Federation
Cand. Sci. (Eng.), Associate Professor
A.S. Atanova
Russian Federation
Post-graduate Student
References
1. The New Plastics Economy: Rethinking the Future of Plastics. Ellen MacArthur Foundation, World Economic Forum and McKinsey & Company, Ellen MacArthur Foundation, 2016, 120 p.
2. Ла Мантия Ф. Вторичная переработка пластмасс. СПб., Профессия, 2007. 400 с.
3. Lee S., Yoshida K., Yoshikawa K. Application of waste plastic pyrolysis oil in a direct injection diesel engine: For a small scale non-grid electrification. Energy and Environment Research. 2015. Vol. 5. No. 1. Р. 18—32.
4. Lopez A., Marco d I., Caballero B.M., Laresgoiti M.F., Adrados A., Torres A. Pyrolysis of municipal plastic waste II: influence of raw material composition under catalytic conditions. Waste Managament. 2011. V. 31 (9—10). Р. 1973—1983.
5. Frigo S., Seggiani M., Puccini M., Vitolo S. Liquid fuel production from waste tyre pyrolysis and its utilisation in a Diesel engine. Fuel . 2014. V. 116. Р. 399—408.
6. Lopez G., Olazar M., Artetxe M., Amutio M., Elordi G., Bilbao J. Steam activation of pyrolytic tyre char at different temperatures. J. Anal. Appl. Pyrol. 2008. Vol. 85. Р. 539—543.
7. Kartel M., Sych N., Tsyba M., Strelko V. Preparation of porous carbons by chemical activation of polyethylene terephthalate. Carbon. 2006. V. 44. Р. 1019—1022.
8. Bian Y., Yuan Q., Zhu G. Recycling of Waste Sludge: Preparation and Application of Sludge-Based Activated Carbon. International Journal of Polymer Science. 2018. Article ID 8320609. 17 p. https://doi.org/10.1155/2018/8320609.
9. Нистратов А.В., Хомутов А.Н., Клушин В.Н. Формирование пористой структуры карбонизатов на основе торфа и полимерных отходов в процессе ступенчатого пиролиза. Успехи в химии и химической технологии. 2010. № 11. С. 29—33.
10. Xiao Juan Jin, Zhi Ming Yu, Zhe Ren, Xin Liu. Preparation of Activated Carbon from Waste Particle Board by Chemical Activation Using Potassium Hydroxide. Advanced Materials Research. 2010. V. 129—131. Р. 1151—1155. https://doi.org/10.4028/www.scientific.net/AMR.129-131.
11. Вайсман Я.И., Глушанкова И.С., Сурков А.А. Анализ методов и технических решений по утилизации отходов потребления поликарбоната. Экология и промышленность России. 2013. Май. С. 36—41.
12. Адсорбция, адсорбенты, адсорбционные процессы в нанопористых материалах. Под ред. А.Ю. Цивадзе. М., Издательская группа "Граница", 2011. 496 с.
13. Сазанов Ю.Н., Грибанов А.В. Карбонизация полимеров. М., Изд-во "НОТ", 2013. 296 с.
14. Raymundo-Pinero E., Azais P., Cacciaguerra T., Cazorla-Amoros D., Linares-Solano A., Beguin F. KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organization. Carbon. 2005. V. 43. Iss. 4. P. 786—795.
15. Глушанкова И.С., Вайсман Я.И. и др. Способ получения углеродного сорбента. Пат. РФ 2616679. Заявл. 2016.03.29. Опубл. 2017.04.18.
Review
For citations:
Vaisman Ya., Glushankova I., Rudakova L., Surkov A., Atanova A. Criteria for the Selection of Synthetic Polymeric Waste as a Raw Material for Producing Carbon Sorbents with Predetermined Properties. Ecology and Industry of Russia. 2020;24(10):13-19. (In Russ.) https://doi.org/10.18412/1816-0395-2020-10-13-19