There was considered a possibility of plastic material recovery, which are parts of solid household waste composition, by means of thermolysis with receiving of textured carbon, which could be used for example under designing. There were selected optimal parameters of synthesis process carrying-out in accordance with recommendations of literature sources. With the aid of SEM-images by taking into account physical and chemical properties of polymer waste was made analysis of unique features of thermal transformations these carbon-containing materials. On the base of EPR-measurements were received data about thermal stability of research materials.