<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">ekip</journal-id><journal-title-group><journal-title xml:lang="ru">Экология и промышленность России</journal-title><trans-title-group xml:lang="en"><trans-title>Ecology and Industry of Russia</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1816-0395</issn><issn pub-type="epub">2413-6042</issn><publisher><publisher-name>ООО "Калвис"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.18412/1816-0395-2025-2-42-48</article-id><article-id custom-type="elpub" pub-id-type="custom">ekip-2847</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>НАУЧНЫЕ РАЗРАБОТКИ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>SCIENTIFIC DEVELOPMENTS</subject></subj-group></article-categories><title-group><article-title>Моделирование и технико-экономический анализ сверхкритических флюидных методов переработки промышленного водного отхода ПАО "Казаньоргсинтез" применительно к модельному стоку</article-title><trans-title-group xml:lang="en"><trans-title>Modeling and Technical and Economic Analysis of Supercritical Fluid Methods for Industrial Wastewater Treatment of "Kazanorgsintez" PJSC in Relation to Model Runoff</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Габитова</surname><given-names>А.Р.</given-names></name><name name-style="western" xml:lang="en"><surname>Gabitova</surname><given-names>A.R.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. техн. наук, доцент</p></bio><bio xml:lang="en"><p>Cand. Sci. (Eng.), Associate Professor</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Аетов</surname><given-names>А.У.</given-names></name><name name-style="western" xml:lang="en"><surname>Aetov</surname><given-names>A.U.</given-names></name></name-alternatives><bio xml:lang="ru"><p>зав. лабораторией</p></bio><bio xml:lang="en"><p>Head of the Laboratory</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Зарипов</surname><given-names>З.И.</given-names></name><name name-style="western" xml:lang="en"><surname>Zaripov</surname><given-names>Z.I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р техн. наук, профессор</p></bio><bio xml:lang="en"><p>Dr. Sci. (Eng.), Professor</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Гумеров</surname><given-names>Ф.М.</given-names></name><name name-style="western" xml:lang="en"><surname>Gumerov</surname><given-names>F.M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р. техн. наук, зав. кафедрой</p></bio><bio xml:lang="en"><p>Dr. Sci. (Eng.), Professor, Head of the Department</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Усманов</surname><given-names>Р.А.</given-names></name><name name-style="western" xml:lang="en"><surname>Usmanov</surname><given-names>R.A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р техн. наук, профессор</p></bio><bio xml:lang="en"><p>Dr. Sci. (Eng.), Professor</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Мазанов</surname><given-names>С.В.</given-names></name><name name-style="western" xml:lang="en"><surname>Mazanov</surname><given-names>S.V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. техн. наук, доцент</p></bio><bio xml:lang="en"><p>Cand. Sci. (Eng.), Associate Professor</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Казанский национальный исследовательский технологический университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Kazan National Research Technological University</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>18</day><month>02</month><year>2025</year></pub-date><volume>29</volume><issue>2</issue><fpage>42</fpage><lpage>48</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; ООО "Калвис", 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">ООО "Калвис"</copyright-holder><copyright-holder xml:lang="en">ООО "Калвис"</copyright-holder><license xlink:href="https://www.ecology-kalvis.ru/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://www.ecology-kalvis.ru/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://www.ecology-kalvis.ru/jour/article/view/2847">https://www.ecology-kalvis.ru/jour/article/view/2847</self-uri><abstract><p>В программном пакете Aspen Hysys (версия 12) с помощью Aspen Process Economic Analyzer проведено технико-экономическое сопоставление возможностей двух различных вариантов очистки фенолсодержащих водных отходов ПАО "Казаньоргсинтез" при использовании экстракционного процесса и в результате проведения процесса окисления органических компонентов водного стока. Выполнено моделирование и масштабирование этих процессов для стока, подаваемого с массовым расходом в 1000 кг/ч. Дана оценка эксплуатационных затрат на реализацию каждого из исследуемых вариантов.</p></abstract><trans-abstract xml:lang="en"><p>In the software package Aspen Hysys (version 12) with the help of Aspen Process Economic Analyzer, a technical and economic comparison of the possibilities of two different variants for phenol-containing aqueous water waste treatment at "Kazanorgsintez" PJSC using the extraction process and as a result of oxidation of organic components of the water runoff was carried out. Modeling and scaling of these processes for a runoff fed at a mass flow rate of 1000 kg/h was performed An estimation of operating costs for realization of each of the investigated variants is given.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>моделирование</kwd><kwd>технико-экономический анализ</kwd><kwd>промышленные отходы</kwd><kwd>сверхкритическая флюидная экстракция</kwd><kwd>окисление в сверхкритической водной среде</kwd></kwd-group><kwd-group xml:lang="en"><kwd>modeling</kwd><kwd>technical and economic analysis</kwd><kwd>industrial waste</kwd><kwd>supercritical fluid extraction</kwd><kwd>oxidation in supercritical aqueous media</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Хайрутдинов В.Ф., Гумеров Ф.М., Хабриев И.Ш. и др. Утилизация древесных железнодорожных шпал с использованием сверхкритического флюидного экстракционного процесса. Экология и промышленность России. 2020. Т. 24. № 9. С. 4—10.</mixed-citation><mixed-citation xml:lang="en">Хайрутдинов В.Ф., Гумеров Ф.М., Хабриев И.Ш. и др. Утилизация древесных железнодорожных шпал с использованием сверхкритического флюидного экстракционного процесса. Экология и промышленность России. 2020. Т. 24. № 9. С. 4—10.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Gros Q., Duval J., West C., Lesellier E. On-line supercritical fluid extraction-supercritical fluid chromatography (SFE-SFC) at a glance. A coupling story. TrAC Trends in Analytical Chemistry. 2021. Vol. 144. 116433.</mixed-citation><mixed-citation xml:lang="en">Gros Q., Duval J., West C., Lesellier E. On-line supercritical fluid extraction-supercritical fluid chromatography (SFE-SFC) at a glance. A coupling story. TrAC Trends in Analytical Chemistry. 2021. Vol. 144. 116433.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Аетов А.У., Усманов Р.А., Мазанов С.В., Гумеров Ф.М. Переработка молибденсодержащего водного стока в сверхкритических условиях. Цветные металлы. 2020. №7. С. 68—73.</mixed-citation><mixed-citation xml:lang="en">Аетов А.У., Усманов Р.А., Мазанов С.В., Гумеров Ф.М. Переработка молибденсодержащего водного стока в сверхкритических условиях. Цветные металлы. 2020. №7. С. 68—73.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Мазанов С.В., Фан К.М., Аетов А.У. и др. Окисление органических соединений в сверхкритических флюидных условиях в рамках задачи утилизации промышленных водных стоков ПАО "Нижнекамскнефтехим" И ПАО "Казаньоргсинтез". Экология и промышленность России. 2023. Т. 27. № 4. С. 10—16.</mixed-citation><mixed-citation xml:lang="en">Мазанов С.В., Фан К.М., Аетов А.У. и др. Окисление органических соединений в сверхкритических флюидных условиях в рамках задачи утилизации промышленных водных стоков ПАО "Нижнекамскнефтехим" И ПАО "Казаньоргсинтез". Экология и промышленность России. 2023. Т. 27. № 4. С. 10—16.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang F., Li Yu., Liang Zh., Wu T. Energy conversion and utilization in supercritical water oxidation systems. A review. Biomass and Bioenergy. 2022. Vol. 156. 106322. https://doi.org/10.1016/j.biombioe.2021.106322.</mixed-citation><mixed-citation xml:lang="en">Zhang F., Li Yu., Liang Zh., Wu T. Energy conversion and utilization in supercritical water oxidation systems. A review. Biomass and Bioenergy. 2022. Vol. 156. 106322. https://doi.org/10.1016/j.biombioe.2021.106322.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Leila M., Ratiba D., Al-Marzouqi Ali-H. Experimental and mathematical modelling data of green process of essential oil extraction: Supercritical CO2 extraction. Materials Today. Proceedings. 2022. Vol. 49. Part 4, P. 1023—1029.</mixed-citation><mixed-citation xml:lang="en">Leila M., Ratiba D., Al-Marzouqi Ali-H. Experimental and mathematical modelling data of green process of essential oil extraction: Supercritical CO2 extraction. Materials Today. Proceedings. 2022. Vol. 49. Part 4, P. 1023—1029.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Cocero M.J., Sanz M.T., Fernández‐Polanco F. Study of alternatives for the design of a mobile unit for wastewater treatment by supercritical water oxidation. Journal of Chemical Technology and Biotechnology. 2001. Vol. 76. P. 257—264.</mixed-citation><mixed-citation xml:lang="en">Cocero M.J., Sanz M.T., Fernández‐Polanco F. Study of alternatives for the design of a mobile unit for wastewater treatment by supercritical water oxidation. Journal of Chemical Technology and Biotechnology. 2001. Vol. 76. P. 257—264.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang F., Chen J., Su Ch., Ma Ch. Energy Consumption and Economic Analyses of a Supercritical Water Oxidation System with Oxygen Recovery. Processes. 2018. Vol. 6. No 11. 224.</mixed-citation><mixed-citation xml:lang="en">Zhang F., Chen J., Su Ch., Ma Ch. Energy Consumption and Economic Analyses of a Supercritical Water Oxidation System with Oxygen Recovery. Processes. 2018. Vol. 6. No 11. 224.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Donatini F., Gigliucci G., Riccardi J., Schiavetti M., Gabbrielli R. Supercritical water oxidation of coal in power plants with low CO2 emissions. Energy. 2009. Vol. 34. P. 2144—2150.</mixed-citation><mixed-citation xml:lang="en">Donatini F., Gigliucci G., Riccardi J., Schiavetti M., Gabbrielli R. Supercritical water oxidation of coal in power plants with low CO2 emissions. Energy. 2009. Vol. 34. P. 2144—2150.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Xiao Z., Qing W., Leming C. Modeling for supercritical water oxidation process of sludge using Aspen plus. Computers Appl. Chem. 2017. Vol. 34. 973.</mixed-citation><mixed-citation xml:lang="en">Xiao Z., Qing W., Leming C. Modeling for supercritical water oxidation process of sludge using Aspen plus. Computers Appl. Chem. 2017. Vol. 34. 973.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Rodrigues V.H., De Melo M.M.R., Silva C.M. Simulation and techno-economic optimization of the supercritical CO2 extraction of Eucalyptus globulus bark at industrial scale. Journal of Supercritical Fluids. 2019. Vol. 145. P. 169—180.</mixed-citation><mixed-citation xml:lang="en">Rodrigues V.H., De Melo M.M.R., Silva C.M. Simulation and techno-economic optimization of the supercritical CO2 extraction of Eucalyptus globulus bark at industrial scale. Journal of Supercritical Fluids. 2019. Vol. 145. P. 169—180.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Qian L., Wang Sh., Wan Sh., Zhao Sh., Zhang B. Supercritical water gasification and partial oxidation of municipal sewage sludge. An experimental and thermodynamic study. International Journal of hydrogen energy. 2021. Vol. 46. P. 89—99.</mixed-citation><mixed-citation xml:lang="en">Qian L., Wang Sh., Wan Sh., Zhao Sh., Zhang B. Supercritical water gasification and partial oxidation of municipal sewage sludge. An experimental and thermodynamic study. International Journal of hydrogen energy. 2021. Vol. 46. P. 89—99.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Cocero M.J., Alonso E., Torío R., Vallelado D., Sanz T., Fdz-Polanco F. Supercritical Water Oxidation for Poly(ethylene terephthalate) Industry Effluents. Ind. Eng. Chem. Res. 2000. Vol. 39. No 12. P. 4652—4657.</mixed-citation><mixed-citation xml:lang="en">Cocero M.J., Alonso E., Torío R., Vallelado D., Sanz T., Fdz-Polanco F. Supercritical Water Oxidation for Poly(ethylene terephthalate) Industry Effluents. Ind. Eng. Chem. Res. 2000. Vol. 39. No 12. P. 4652—4657.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Гумеров Ф.М., Зарипов З.И., Мазанов С.В. и др. Некоторые характеристики термодинамических систем и их влияние на эффективность извлечения ценных компонентов промышленного водного стока ПАО "Казань-оргсинтез" методом сверхкритической флюидной экстракции. СКФ-ТП. 2022. Т. 17. № 4. С. 3—13.</mixed-citation><mixed-citation xml:lang="en">Гумеров Ф.М., Зарипов З.И., Мазанов С.В. и др. Некоторые характеристики термодинамических систем и их влияние на эффективность извлечения ценных компонентов промышленного водного стока ПАО "Казань-оргсинтез" методом сверхкритической флюидной экстракции. СКФ-ТП. 2022. Т. 17. № 4. С. 3—13.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Mazanov S.V., Phan Q.M., Aetov A.U. et all. Heterogeneous Catalytic and Non-Catalytic Supercritical Water Oxidation of Organic Pollutants in Industrial Wastewaters Effect of Operational Parameters. Journal Symmetry. 2023. Vol. 15 (2). 340.</mixed-citation><mixed-citation xml:lang="en">Mazanov S.V., Phan Q.M., Aetov A.U. et all. Heterogeneous Catalytic and Non-Catalytic Supercritical Water Oxidation of Organic Pollutants in Industrial Wastewaters Effect of Operational Parameters. Journal Symmetry. 2023. Vol. 15 (2). 340.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
