<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">ekip</journal-id><journal-title-group><journal-title xml:lang="ru">Экология и промышленность России</journal-title><trans-title-group xml:lang="en"><trans-title>Ecology and Industry of Russia</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1816-0395</issn><issn pub-type="epub">2413-6042</issn><publisher><publisher-name>ООО "Калвис"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.18412/1816-0395-2023-5-28-33</article-id><article-id custom-type="elpub" pub-id-type="custom">ekip-2376</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>НАУЧНЫЕ РАЗРАБОТКИ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>SCIENTIFIC DEVELOPMENTS</subject></subj-group></article-categories><title-group><article-title>Идентификация состава окрашенного синтетического гипса, получаемого в виде отходов при производстве ванадия</article-title><trans-title-group xml:lang="en"><trans-title>Identity of the Composition of Colored Technical Gypsum Obtained as Waste of Vanadium Production</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Бессмертный</surname><given-names>В.С.</given-names></name><name name-style="western" xml:lang="en"><surname>Bessmertny</surname><given-names>V.S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р техн. наук, профессор</p></bio><bio xml:lang="en"><p>Dr. Sci. (Eng.), Professor</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Платова</surname><given-names>Р.А.</given-names></name><name name-style="western" xml:lang="en"><surname>Platova</surname><given-names>R.A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. техн. наук, доцент</p></bio><bio xml:lang="en"><p>Cand. Sci. (Eng.), Associate Professor</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Платов</surname><given-names>Ю.Т.</given-names></name><name name-style="western" xml:lang="en"><surname>Platov</surname><given-names>Yu.T.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р техн. наук, профессор</p></bio><bio xml:lang="en"><p>Dr. Sci. (Eng.), Professor</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Рассулов</surname><given-names>В.А.</given-names></name><name name-style="western" xml:lang="en"><surname>Rassulov</surname><given-names>V.A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. геол.-мин. наук</p></bio><bio xml:lang="en"><p>Cand. Sci. (Geol.-Mineral.)</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Бондаренко</surname><given-names>М.А.</given-names></name><name name-style="western" xml:lang="en"><surname>Bondarenko</surname><given-names>M.A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>аспирант</p></bio><bio xml:lang="en"><p>Post-graduate Student</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Варфоломеева</surname><given-names>С.В.</given-names></name><name name-style="western" xml:lang="en"><surname>Varfolomeeva</surname><given-names>S.V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>аспирант</p></bio><bio xml:lang="en"><p>Post-graduate Student</p></bio><email xlink:type="simple">podpiska@kalvis.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Белгородский государственный технологический университет им. В.Г. Шухова</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Belgorod State Technological University named aftere V.G. Shukhov</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Российский экономический университет им. Г. В. Плеханова</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Russian Economic University named after G. V. Plekhanov</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Всероссийский институт минерального сырья им. Н.М. Федоровского</institution><country>Россия</country></aff><aff xml:lang="en"><institution>All-Russian Research Institute of Mineral Resources named after N.M. Fedorovsky</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2023</year></pub-date><pub-date pub-type="epub"><day>16</day><month>05</month><year>2023</year></pub-date><volume>27</volume><issue>5</issue><fpage>28</fpage><lpage>33</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; ООО "Калвис", 2023</copyright-statement><copyright-year>2023</copyright-year><copyright-holder xml:lang="ru">ООО "Калвис"</copyright-holder><copyright-holder xml:lang="en">ООО "Калвис"</copyright-holder><license xlink:href="https://www.ecology-kalvis.ru/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://www.ecology-kalvis.ru/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://www.ecology-kalvis.ru/jour/article/view/2376">https://www.ecology-kalvis.ru/jour/article/view/2376</self-uri><abstract><p>Представлены результаты идентификации состава окрашенного синтетического гипса, получаемого в виде отходов при производстве ванадия на АО "ЕВРАЗ Ванадий Тула". Показано, что при термической обработке при 700 °С происходит преобразование гипса в ангидрит. Установлено, что окрашивание отходов связано с наличием в их составе гидроксида марганца и оксида ванадия, взаимодействие которых при термической обработке приводит к образованию ванадата марганца Mn2V2O7, что обусловливает изменение цветового тона продукта. Рекомендовано использование окрашенных гипсосодержащих отходов и продуктов их термической обработки в качестве декоративных материалов строительного назначения.</p></abstract><trans-abstract xml:lang="en"><p>The results of identity composition of coloured technicl gypsum as a waste product of vanadium production at OAO "EVRAZ Vanadiy Tula" were presented. It was shown that gypsum is converted into anhydrite during heat treatment at 700 °C. It was proved that waste coloring is due to the presence of manganese hydroxide and vanadium oxide, their interaction during heat treatment forms manganese vanadate Mn2V2O7 and changes the color tone of the product. As decorative building materials, it is recommended to use colored gypsum-containing waste and products of their heat treatment.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>отходы производства</kwd><kwd>гипс</kwd><kwd>ангидрит</kwd><kwd>ванадат марганца</kwd><kwd>цвет материала</kwd><kwd>инфракрасный спектр</kwd></kwd-group><kwd-group xml:lang="en"><kwd>industrial waste</kwd><kwd>gypsum</kwd><kwd>anhydrite</kwd><kwd>manganese vanadate</kwd><kwd>material color</kwd><kwd>infrared spectrum</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Жукова Ю.М., Никулина С.Н., Яковлева О.В., Чериканова Е.А. Анализ основных тенденций развития системы обращения с отходами в России: проблемы и перспективы. Экология и промышленность России. 2020. №24(8). С. 66—71.</mixed-citation><mixed-citation xml:lang="en">Жукова Ю.М., Никулина С.Н., Яковлева О.В., Чериканова Е.А. Анализ основных тенденций развития системы обращения с отходами в России: проблемы и перспективы. Экология и промышленность России. 2020. №24(8). С. 66—71.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Van Ewijk S., Stegemann J.A. Recognising waste use potential to achieve a circular economy. Waste Management. 2020. V. 105. P. 1—7.</mixed-citation><mixed-citation xml:lang="en">Van Ewijk S., Stegemann J.A. Recognising waste use potential to achieve a circular economy. Waste Management. 2020. V. 105. P. 1—7.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Lushnikova N., Dvorkin L. Sustainability of gypsum products as a construction material. Sustainability of Construction Materials. Woodhead Publishing. 2016. P. 643—681.</mixed-citation><mixed-citation xml:lang="en">Lushnikova N., Dvorkin L. Sustainability of gypsum products as a construction material. Sustainability of Construction Materials. Woodhead Publishing. 2016. P. 643—681.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Romanovski V., Klyndyuk A., Kamarou M. Green approach for low-energy direct synthesis of anhydrite from industrial wastes of lime mud and spent sulfuric acid. Journal of Environmental Chemical Engineering. 2021. V. 9. № 6. 106711.</mixed-citation><mixed-citation xml:lang="en">Romanovski V., Klyndyuk A., Kamarou M. Green approach for low-energy direct synthesis of anhydrite from industrial wastes of lime mud and spent sulfuric acid. Journal of Environmental Chemical Engineering. 2021. V. 9. № 6. 106711.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Kamarou M., Korob N., Kwapinski W., Romanovski V. High-quality gypsum binders based on synthetic calcium sulfate dihydrate produced from industrial waste. Journal of Industrial and Engineering Chemistry. 2021. V. 100. P. 324—332.</mixed-citation><mixed-citation xml:lang="en">Kamarou M., Korob N., Kwapinski W., Romanovski V. High-quality gypsum binders based on synthetic calcium sulfate dihydrate produced from industrial waste. Journal of Industrial and Engineering Chemistry. 2021. V. 100. P. 324—332.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Sáez-Pérez M.P., Durán-Suárez J.A., Verdú-Vázquez A., Gil-López T. Characterization and chromatic evaluation of gypsum-based pastes for construction and heritage restoration.Construction and Building Materials. 2021. V. 307. 124981.</mixed-citation><mixed-citation xml:lang="en">Sáez-Pérez M.P., Durán-Suárez J.A., Verdú-Vázquez A., Gil-López T. Characterization and chromatic evaluation of gypsum-based pastes for construction and heritage restoration.Construction and Building Materials. 2021. V. 307. 124981.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Sáez-Pérez M.P., Durán-Suárez J.A., Verdú-Vázquez A., Gil-López T. Study and Characterization of Special Gypsum-Based Pastes for Their Use as a Replacement Material in Architectural Restoration and Construction. Materials. 2022. V. 15. № 17. 5877.</mixed-citation><mixed-citation xml:lang="en">Sáez-Pérez M.P., Durán-Suárez J.A., Verdú-Vázquez A., Gil-López T. Study and Characterization of Special Gypsum-Based Pastes for Their Use as a Replacement Material in Architectural Restoration and Construction. Materials. 2022. V. 15. № 17. 5877.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Balan E., Aufort J., Pouillé S., Dabos M., Blanchard M., Lazzeri M., Blamart D. Infrared spectroscopic study of sulfate-bearing calcite from deep-sea bamboo coral. European Journal of Mineralogy. 2017. V. 29. № 3. P. 397—408.</mixed-citation><mixed-citation xml:lang="en">Balan E., Aufort J., Pouillé S., Dabos M., Blanchard M., Lazzeri M., Blamart D. Infrared spectroscopic study of sulfate-bearing calcite from deep-sea bamboo coral. European Journal of Mineralogy. 2017. V. 29. № 3. P. 397—408.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Bishop J.L., Lane M.D., Dyar M.D., King S.J., Brown A.J., Swayze G.A. Spectral properties of Ca-sulfates: Gypsum, bassanite, and anhydrite. American Mineralogist. 2014. V. 99. № 10. P. 2105—2115.</mixed-citation><mixed-citation xml:lang="en">Bishop J.L., Lane M.D., Dyar M.D., King S.J., Brown A.J., Swayze G.A. Spectral properties of Ca-sulfates: Gypsum, bassanite, and anhydrite. American Mineralogist. 2014. V. 99. № 10. P. 2105—2115.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Safarov R.Z., Kargin J.B., Aibuldinov Y.K., Zhandildenova A.K., Makhmutov B.B., Sviderskiy A.K., Vatin N.I. Structure and Content Analysis of Raw Materials for Production of Trimanganese Tetraoxide Pigment. Crystals. 2021. V. 11. № 12. 1460.</mixed-citation><mixed-citation xml:lang="en">Safarov R.Z., Kargin J.B., Aibuldinov Y.K., Zhandildenova A.K., Makhmutov B.B., Sviderskiy A.K., Vatin N.I. Structure and Content Analysis of Raw Materials for Production of Trimanganese Tetraoxide Pigment. Crystals. 2021. V. 11. № 12. 1460.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Chukanov N.V., Varlamov D.A., Pekov I.V., Zubkova N.V., Kasatkin A.V., Britvin S.N. Coupled substitutions in natural MnO (OH) polymorphs: Infrared spectroscopic investigation. Minerals. 2021. V. 11. № 9. 969.</mixed-citation><mixed-citation xml:lang="en">Chukanov N.V., Varlamov D.A., Pekov I.V., Zubkova N.V., Kasatkin A.V., Britvin S.N. Coupled substitutions in natural MnO (OH) polymorphs: Infrared spectroscopic investigation. Minerals. 2021. V. 11. № 9. 969.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Kang L., Zhang M., Liu Z.H., Ooi K. IR spectra of manganese oxides with either layered or tunnel structures. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2007. V. 67. № 3—4. P. 864—869.</mixed-citation><mixed-citation xml:lang="en">Kang L., Zhang M., Liu Z.H., Ooi K. IR spectra of manganese oxides with either layered or tunnel structures. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2007. V. 67. № 3—4. P. 864—869.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Julien C.M., Massot M., Poinsignon C. Lattice vibrations of manganese oxides: Part I. Periodic structures. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2004. V. 60. № 3. P. 689—700.</mixed-citation><mixed-citation xml:lang="en">Julien C.M., Massot M., Poinsignon C. Lattice vibrations of manganese oxides: Part I. Periodic structures. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2004. V. 60. № 3. P. 689—700.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Wen J., Jiang T., Sun H., Yu T. Novel Understanding of Simultaneous Extraction of Vanadium and Manganese from Vanadium Slag and Low-Grade Pyrolusite Based on Selective Oxidation—Reduction Roasting. ACS Sustainable Chemistry &amp; Engineering. 2020. V. 8. № 15. P. 5927—5936.</mixed-citation><mixed-citation xml:lang="en">Wen J., Jiang T., Sun H., Yu T. Novel Understanding of Simultaneous Extraction of Vanadium and Manganese from Vanadium Slag and Low-Grade Pyrolusite Based on Selective Oxidation—Reduction Roasting. ACS Sustainable Chemistry &amp; Engineering. 2020. V. 8. № 15. P. 5927—5936.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Cao G.J., Zheng S.T., Fang W.H., Yang G.Y. (en) Mn2 (V2O7): A 3D manganese vanadate built by Mn—O layers and two types of pillars of V2O7 and en bridges. Inorganic Chemistry Communications. 2010. V. 13. № 7. P. 834—836.</mixed-citation><mixed-citation xml:lang="en">Cao G.J., Zheng S.T., Fang W.H., Yang G.Y. (en) Mn2 (V2O7): A 3D manganese vanadate built by Mn—O layers and two types of pillars of V2O7 and en bridges. Inorganic Chemistry Communications. 2010. V. 13. № 7. P. 834—836.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
