ekipЭкология и промышленность РоссииEcology and Industry of Russia1816-03952413-6042ООО "Калвис"10.18412/1816-0395-2019-1-15-19ekip-1181Research ArticleНАУЧНЫЕ РАЗРАБОТКИSCIENTIFIC DEVELOPMENTSПрименение каркасных соединений для очистки окрашенных сточных вод пищевых производствApplication of Metal-Organic Frameworks for Purification of Colored Waste Water of Food IndustryВласоваЕ.А.VlasovaE.A.

канд. хим. наук, науч. сотрудник

Cand. Sci. (Chem.), Research Fellow

podpiska@kalvis.ruКулешоваН.К.KuleshovaN.K.

магистрант

Undergraduate Student

podpiska@kalvis.ruАфанасьеваА.В.Afanas'evaA.V.

магистрант

Undergraduate Student

podpiska@kalvis.ruИвановский государственный химико-технологический университетРоссияIvanovo State University of Chemistry and TechnologyRussian Federation2019150120192311519Copyright © ООО "Калвис", 20192019ООО "Калвис"ООО "Калвис"https://www.ecology-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.ecology-kalvis.ru/jour/article/view/1181

Синтезированы алюмо-, железо- и титансодержащие металлоорганические каркасные соединения на основе терефталевой кислоты и охарактеризованы с использованием широкого круга физико-химических методов: БЭТ, рентгенофазового и термогравиметрического анализов, ИК спектроскопии. Изучена сорбционная активность полученных каркасных соединений в отношении пищевых красителей – Индигокармина, Тартразина и Понсо 4R в широком интервале pH. Показано, что все исследуемые красители лучше сорбируются в кислых средах. Установлено, что указанные сорбенты сохраняют работоспособность не менее пяти циклов (с учетом регенерации путем обработки этанолом). Металлоорганические каркасные соединения могут быть использованы в качестве эффективных и легко регенерируемых сорбентов для очистки сточных вод от органических красителей пищевых производств.

Aluminum-, iron- and titanium-containing metal-organic frameworks based on terephthalic acid was prepared and was characterized using BET, XRD, TGA and FT-IR techniques. Sorption of food dyes Indigo carmine, Tartrazine and Ponceau 4R with synthesized metal-organic frameworks was investigated in wide range of pH. It was established that the sorption of all dyes is better in acid media. It is found that the used metal-organic frameworks can be easily recycled at least five times, via ethanol washing. Metal-organic frameworks can be used as effective and easy regenerable sorbents for wastewater treatment from organic dyes of food industry.

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The authors declare that there are no conflicts of interest present.